A green luminescent 1-D helical tubular dipyrazol-bridged cadmium(II) complex: a coordination tube included in a supramolecular tube.
نویسندگان
چکیده
A 1-D helical tubular cadmium coordination polymer, [Cd(H2Me4bpz)(H2bidc)2]n (1, H2Me4bpz = 3,3',5,5'-tetramethyl-4,4'-bipyrazole; H3bidc = benzimidazole-5,6-dicarboxylic acid) was hydrothermally synthesized and characterized by means of elemental analyses, PXRD, IR, 2D IR correlation spectra, solid UV, TG analysis, luminescence spectroscopy and single crystal X-ray diffraction. The crystal structure of 1 is a unique example of a 1D helical tube-in-tube structure. Interestingly, the [Cd(H2Me4bpz)] coordination helical tube is included in the [Cd(H2bidc)] supramolecular helical tube with the same handness. The compound displays a green luminescence upon excitation at 397 nm.
منابع مشابه
A cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions.
It is a challenge to synthesize a porous tubular coordination polymer with magnetic properties. Utilizing [Fe(II)(bipy)(CN)4](2-) (bipy = 2,2'-bipyridine) as the building block to react with Mn(2+), we successfully synthesized a cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions. The inner surface of the heterometallic tube is hydrophilic, whereas the outer surf...
متن کاملConstruction of 2-D lanthanide coordination frameworks: syntheses, structures and luminescent property{
A series of layered lanthanide coordination frameworks [Ln4(NIPH)6(H2O)4]?(4,49-bipy) [Ln = La (1), Pr (2)], [La(NIPH)2(H2O)2]?0.5(4,49-H2bipy) (3), Ln(NIPH)2(H2O)2]?0.5(4,49-H2bipy)?2H2O [Ln =Pr (4), Nd (5)], and [Ln(NIPH)2]?0.5(4,49-H2bipy) [Ln = Sm (6), Eu (7), Tb (8), Ho (9), Yb (10)] (NIPH = 5-nitroisophthalate and 4,49-bipy = 4,49-bipyridine) have been synthesized under hydrothermal condi...
متن کاملTwo-dimensional Manganese(II) Coordination Polymer Complex Containing Aqua, Diethyl Phosphate and Chloride Ligands: Synthesis, Spectroscopic Characterization, Thermal Analyses, and Crystal Structure
A new two-dimensional manganese(II) coordination polymer, [Mn(μ-DEP)(μ-Cl)(H2O)2]n (1) (DEP is diethyl phosphate), was prepared from the reaction of MnCl2.4H2O and TEP (TEP is triethyl phosphate) ligand in mixture of H2O/CH3OH (1:10) at 40 °C. Suitable crystals of this complex for crystal structure determination were obtained by slow evaporation of the produced colorless solution at room temper...
متن کاملSynthesis, Crystal Structure and Luminescent Property of Cd (II) Complex with N-Benzenesulphonyl-L-leucine
A new trinuclear Cd (II) complex [Cd3(L)6(2,2-bipyridine)3] [L = N-phenylsulfonyl-L-leucinato] has been synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. The results show that the complex belongs to the orthorhombic, space group P212121 with a = 16.877(3) Å, b = 22.875(5) Å, c = 29.495(6) Å, α = β = γ = 90°, V = 11387(4) Å, Z = 4, Dc= 1.416 μ...
متن کاملInvestigation on Turbulent Nanofluid Flow in Helical Tube in Tube Heat Exchangers
In this study, the thermal characteristics of turbulent nanofluid flow in a helical tube in the tube heat exchanger (HTTHE) were assessed numerically through computational fluid dynamics (CFD) simulation. The findings of both the turbulent models: realizable k-epsion (k-ε) and re-normalisation group (RNG) k-epsilon were compared. The temperature distribution contours show that realizable and RN...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Dalton transactions
دوره 42 29 شماره
صفحات -
تاریخ انتشار 2013